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Herein, we claimed the development of stereodivergent assembly of tetrahydro-γ-carbolines via a synergistic Cu/Ir catalyst system to realize a stereodivergent allylation of aldimine esters and indolyl allylic carbonates followed by a spontaneous intramolecular iso-Pictet-Spengler cyclization. The stereochemical result of your cascade process is ex

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